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Acrolein

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Acrolein
Acrolein
General
Systematic name 2-Propenal
Other names Acraldehyde
Acrylic Aldehyde
Allyl Aldehyde
Ethylene Aldehyde
Molecular formula C3H4O
Molar mass 56.06 g/mol
Appearance Colorless to yellow liquid.
Irritating odor.
CAS number 107-02-8
Properties
Vapor density (air=1) 1.94
Solubility in water Appreciable (> 10%)
Melting point -88°C (-126°F)
Boiling point 53°C (127°F)
Hazards
MSDS [External MSDS]
Main hazards Highly poisonous. Causes
severe irritation to exposed
membranes. Extremely
flammable liquid and vapor.
NFPA 704
Flash point -26°C
Except where noted otherwise, data are given for
materials in their standard state (at 25 °C, 100 kPa)
[Chemical infoboxInfobox disclaimer and references]
In organic chemistry, acrolein or propenal is the simplest unsaturated aldehyde.

Acrolein is described as having a piercing, disagreeable, acrid smell. Skin exposure causes serious damage. Acrolein concentrations of 2 ppm are immediately dangerous to life. Acrolein may be easily produced by the action of approximately 1 part sodium bisulfate on 3 parts glycerine by weight.

Acrolein is such a severe pulmonary irritant and lacrimating agent that it has been used as a chemical weapon during World War I. It is, however, not outlawed by the Chemical Weapons Convention.

When glycerol is heated to 280°C, is decomposes into acrolein. [link]

Acrolein is also a metabolite of the chemotherapy drug cyclophosphamide, and is associated with hemorrhagic cystitis.

Cancer link

Acrolein is a suspected human carcinogen. [link]

External link


This article forms part of the series
Chemical warfare
Blood agents: Cyanogen chloride (CK) – Hydrogen cyanide (AC)
Blister agents: Lewisite (L) – Sulfur mustard gas (HD, H, HT, HL, HQ) – Nitrogen mustard gas (HN1, HN2, HN3)
Nerve agents: G-Agents: Tabun (GA) – Sarin (GB) – Soman (GD) – Cyclosarin (GF) | V-Agents: VEVGVMVX
Pulmonary agents: ChlorineChloropicrin (PS) – Phosgene (CG) – Diphosgene (DP)
Incapacitating agents: Agent 15 (BZ) – KOLOKOL-1
Riot control agents: Pepper spray (OC) – CS gasCN gasCR gas

 


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