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Conjugate acid

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Within the Brønsted-Lowry (protonic) theory of acids and bases, a conjugate acid is the acid member, HX, of a pair of two compounds that transform into each other by gain or loss of a proton. The base produced, X-, is called the conjugate base. In aqueous solution, the chemical reaction involved is of the form

HX + H2O ↔ X + H3O+
This principle is discussed in detail in the article on acid-base reaction theories.

Tabulated below are several examples of conjugate acid-base pairs. Acid strength decreases and base strength increases down the table. (The dissociation reaction reaches equilibrium further to the right, with more X produced.)

Acid Base
HFSbF5 Fluoroantimonic acid SbF6 Antimony pentaflouride ion
HCl Hydrochloric acid Cl- Chloride ion
H2SO4 Sulphuric acid HSO4 Hydrogen sulphate ion
HNO3 Nitric acid NO3 Nitrate ion
H3O+ Hydronium ion H2O Water
HSO4 Hydrogen sulphate ion SO42− Sulfate ion
H3PO4 Phosphoric acid H2PO4 Dihydrogen phosphate ion
HC2H3O2 Acetic acid C2H3O2- Acetate ion
H2CO3 Carbonic acid HCO3 Hydrogen carbonate ion
H2S Hydrosulphuric acid HS Hydrogen sulphide ion
H2PO4 Dihydrogen phosphate ion HPO42− Hydrogen phosphate ion
NH4+ Ammonium ion NH3 Ammonia
HCO3 Hydrogen carbonate ion CO32− Carbonate ion
HPO42− Hydrogen phosphate ion PO43− Phosphate ion
H2O Water (neutral, pH7) OH Hydroxide ion

 


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