Octanitrocubane

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Octanitrocubane is a powerful high explosive, that - like TNT - is shock-insensitive (not detonated by shock). The octanitrocubane molecule has the same chemical structure as the cubane molecule, C₈H₈, except all eight hydrogen (H) atoms are each replaced by nitro (NO₂) groups.

Octanitrocubane is thought to have 20 to 25 percent greater performance than HMX (octogen), the state-of-the-art military explosive as of year 2000. This increase in power is due to its greater molecular weight and its highly expansive breakdown into 8CO₂ + 4N₂, as well as to the presence of strained chemical bonds in the molecule. In addition, Octanitrocubane requires no external oxygen source to decompose, produces no water vapor (making it less visible), and both the chemical itself and its decomposition products are considered non-toxic.

Small amounts have been synthesized in the lab, but not enough for performance testing as an explosive.

Octanitrocubane was first synthesized by Philip Eaton and Mao-Xi Zhang at the University of Chicago in 1999, with the structure proven by crystallographer Richard Gilardi of the US Naval Research Laboratory.

"Hepta- and Octanitrocubanes", Mao-Xi Zhang, Philip E. Eaton, and Richard Gilardi; Angew. Chem. Int. Ed. 2000, 39, No. 2, pages 401-404

Its R.E. factor is about 2.7.

See also

External links

• [Powerful explosive blasts onto scene Science News Online, Jan. 22, 2000]

• For a full list of external links to MSDSs, spectroscopic data, commercial chemicals suppliers etc. for this compound, see [Chemical sources].

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