Organometallic chemistry
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Organometallic chemistry is the study of chemical compounds containing bonds between carbon and a metal. Often this definition is too strict however, since many compounds without such bonds are chemically similar. An appropriate alternative may be "compounds containing metal-element bonds of a largely covalent character". Organometallic chemistry combines aspects of inorganic chemistry and organic chemistry. Organometallic compounds are distinguished by the prefix "organo-".
Some typical organometallic compounds are
- organozinc compounds such as ClZnCH2C(=O)OEt (chloro(ethoxycarbonylmethyl)zinc),
- organocuprates such as Li[CuMe2] (lithium dimethylcuprate),
- organomagnesium compounds such as the Grignard reagents MeMgI (methylmagnesium iodide) and MgEt2 (diethylmagnesium), and
- organolithium compounds such as n-butyllithium.
- organopalladium compounds
Organometallic compounds often find practical use in stoichiometric and catalytically active compounds, for example in the processing of petroleum products and the production of polymers.
The 18-Electron rule and the isolobal principle are concepts that help to understand chemical bonding and reactivity in organometallic compounds.
Key reaction mechanisms are oxidative addition, reductive elimination, transmetalation, electron transfer and organometallic substitution reactions.
Organometallic chemistry timeline
- 1760 Louis Claude Cadet de Gassicourt investigates inks based on Cobalt salts and isolates Cacodyl from cobalt mineral containing arsenic
- 1827 Zeise's salt is the first platinum / olefin complex
- 1863 Charles Friedel and James Crafts prepare organochlorosilanes
- 1890 Ludwig Mond discovers Nickel carbonyl
- 1899 Introduction of Grignard reaction
- 1900 Paul Sabatier works on hydrogenation organic compounds with metal catalysts. Hydrogenation of fats kicks off advances in food industry, see margarine
- 1912 Nobel Prize Victor Grignard and Paul Sabatier
- 1930 Henry Gilman works on lithium cuprates, see Gilman reagent
- 1963 Nobel prize for Karl Ziegler and Giulio Natta on Ziegler-Natta catalyst
- 1965 Discovery of cyclobutadieneiron tricarbonyl
- 1968 Heck reaction
- 1973 Nobel prize Geoffrey Wilkinson and Ernst Otto Fischer on sandwich compounds
- 2005 Nobel prize Yves Chauvin, Robert Grubbs, and Richard Schrock on metal-catalyzed alkene metathesis
Organometallics
- Period 2 elements: organolithium chemistry, organoberyllium chemistry, organoborane chemistry,
- Period 3 elements: organomagnesium chemistry, organoaluminum chemistry, organosilicon chemistry
- Period 4 elements: organonickel chemistry, organocopper chemistry, organozinc chemistry, organogallium chemistry, organogermanium chemistry
- Period 5 elements: organopalladium chemistry, organosilver chemistry, organocadmium chemistry, organoindium chemistry, organotin chemistry
- Period 6 elements: organoplatinum chemistry, organogold chemistry, organomercury chemistry,organothallium chemistry, organolead chemistry
See also
External links
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