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PH indicator

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pH measurement with indicator paper.
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pH measurement with indicator paper.

A pH indicator is a halochromic chemical compound that is added in small amounts to a solution so that the pH (acidity or alkalinity) of the solution can be determined easily. Hence a pH indicator is a chemical detector for hydronium ions (H3O+). Normally, the indicator causes the color of the solution to change depending on the pH.

pH indicators themselves are frequently weak acids or bases. When introduced into a solution, they may bind to H+ (Hydrogen ion) or OH- (hydroxide) ions. The different electron configurations of the bound indicator causes the indicator's color to change.

Because of the subjective determination of color, pH indicators are susceptible to imprecise readings. For applications requiring precise measurement of pH, a pH meter is frequently used.

pH indicators are frequently employed in titrations in analytic chemistry and biology experiments to determine the extent of a chemical reaction.

Tabulated below are several common laboratory pH indicators. Indicators usually exhibit intermediate colors at pH values inside the listed transition range. For example, phenol red exhibits an orange color between pH 6.6 and pH 8.0. The transition range may shift slightly depending on the concentration of the indicator in solution and on the temperature at which it is used.

Indicator Color at low pH Transition pH range (approximate) Color at high pH
Methyl violet yellow 0.0-1.6 blue-violet
Malachite green yellow 0.2-1.8 blue-green
Thymol blue (acid - first transition) red 1.2-2.8 yellow
Methyl yellow (in ethanol) red 2.9-4.0 yellow
Bromophenol blue yellow 3.0-4.6 violet
Congo red blue 3.0-5.2 red
Methyl orange red 3.1-4.4 yellow
Methyl orange in xylene cyanole solution purple 3.2-4.2 green
Bromocresol green yellow 3.8-5.4 blue
Methyl red red 4.2-6.3 yellow
Litmus (Azolitmin) red 4.5-8.3 blue
Bromocresol purple yellow 5.2-6.8 violet
Bromothymol blue yellow 6.0-7.6 blue
Phenol red yellow 6.6-8.0 red
Neutral Red red 6.8-8.0 yellow
Thymol blue (base - second transition) yellow 8.0-9.6 blue
Phenolphthalein colorless 8.2-10.0 pink
Thymolphthalein colorless 9.4-10.6 blue
Alizarin Yellow R yellow 10.1-12.0 orange-red
Indigo carmine blue 11.4-13.0 yellow

Natural pH indicators

 


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