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Plasma (physics)

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This article is about the ionized gas. See also the disambiguation page "plasma" for other uses and meanings
A Plasma lamp, illustrating some of the more complex phenomena of a plasma, including filamentation
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A Plasma lamp, illustrating some of the more complex phenomena of a plasma, including filamentation

In physics and chemistry, a plasma is typically an ionized gas, and is usually considered to be a distinct phase of matter in contrast to solids, liquids, and gases because of its unique properties. "Ionized" means that at least one electron has been dissociated from a proportion of the atoms or molecules. The free electric charges make the plasma electrically conductive so that it responds strongly to electromagnetic fields.

This fourth state of matter was first identified in a discharge tube (or Crookes tube), and so described by Sir William Crookes in 1879 (he called it "radiant matter")Crookes presented a lecture to the British Association for the Advancement of Science, in Sheffield, on Friday, 22nd August 1879 [link] [link]. The nature of the Crookes tube "cathode ray" matter was subsequently identified by English physicist Sir J.J. Thomson in 1897Announced in his evening lecture to the Royal Institution on Friday, 30th April 1897, and published in Philosophical Magazine, 44, 293 [link], and dubbed "plasma" by Irving Langmuir in 1928 I. Langmuir, "[Oscillations in ionized gases]," Proc. Nat. Acad. Sci. U.S., vol. 14, p. 628, 1928, perhaps because it reminded him of a blood plasma G. L. Rogoff, Ed., IEEE Transactions on Plasma Science, vol. 19, p. 989, Dec. 1991. See extract at http://www.plasmacoalition.org/what.htm. Langmuir wrote:

"Except near the electrodes, where there are sheaths containing very few electrons, the ionized gas contains ions and electrons in about equal numbers so that the resultant space charge is very small. We shall use the name plasma to describe this region containing balanced charges of ions and electrons."
Plasma typically takes the form of neutral gas-like clouds or charged ion beams, but may also include dust and grains (called dusty plasmas). [link] They are typically formed by heating and ionizing a gas, stripping electrons away from atoms, thereby enabling the positive and negative charges to move freely.

Common plasmas

Plasmas are the most common phase of matter. Some estimates suggest that up to 99% of the entire visible universe is plasmaD. A. Gurnett, A. Bhattacharjee, Introduction to Plasma Physics: With Space and Laboratory Applications (2005) ([Page 2]). Also K Scherer, H Fichtner, B Heber, "Space Weather: The Physics Behind a Slogan" (2005) ([Page 138]). Since the space between the stars is filled with a plasma, although a very sparse one (see interstellar- and intergalactic medium), essentially the entire volume of the universe is plasma (see astrophysical plasmas). In the solar system, the planet Jupiter accounts for most of the non-plasma, only about 0.1% of the mass and 10−15% of the volume within the orbit of Pluto. Notable plasma physicist Hannes Alfvén also noted that due to their electric charge, very small grains also behave as ions and form part of plasma (see dusty plasmas).

Common forms of plasma include
Artificially produced plasma
Terrestrial plasmas
and astrophysical plasmas

Plasma properties and parameters

Plasma properties are strongly dependent on the bulk (or average) parameters. Some of the most important plasma parameters are the degree of ionization, the plasma temperature, the density and the magnetic field in the plasma region. We explain these parameters, and then describe how plasmas interact with electric and magnetic fields and outline the qualitative differences between plasmas and gases.

Definition of a plasma

The Earth's "plasma fountain", showing oxygen, helium, and hydrogen ions that gush into space from regions near the Earth's poles. The faint yellow gas shown above the north pole represents gas lost from Earth into space; the green gas is the aurora borealis-or plasma energy pouring back into the atmosphere.Plasma fountain  [Source], press release: [Solar Wind Squeezes Some of Earth's Atmosphere into Space]
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The Earth's "plasma fountain", showing oxygen, helium, and hydrogen ions that gush into space from regions near the Earth's poles. The faint yellow gas shown above the north pole represents gas lost from Earth into space; the green gas is the aurora borealis-or plasma energy pouring back into the atmosphere.Plasma fountain [Source], press release: [Solar Wind Squeezes Some of Earth's Atmosphere into Space]

Although a plasma is loosely described as a quasineutral collection of charged particles, a more rigorous definition requires three criteria to be satisfied:

  1. The plasma approximation: Charged particles must be close enough together that each particle influences many nearby charged particles, rather than just the interacting with the closest particle (these collective effects are a distinguishing feature of a plasma). The plasma approximation is valid when the number of electrons within the sphere of influence (the Debye sphere) of a particular particle is large. The average number of particles in the Debye sphere is given by the plasma parameter, Λ.
  2. Bulk interactions: The Debye screening length (defined above) is short compared to the physical size of the plasma. This criterion means that interactions in the bulk of the plasma are more important than those at its edges, where boundaries effects may take place.
  3. Plasma frequency: The electron plasma frequency (measuring plasma oscillations) is large compared to the electron neutral collision frequency. When this condition is valid, plasmas act to shield charges very rapidly (quasineutrality is another defining property of plasmas).

Ranges of plasma parameters

The Heliospheric current sheet, the largest structure in the Solar SystemSee [A Star with two North Poles], resulting from the influence of the Sun's rotating magnetic field on the plasma in the interplanetary medium (Solar Wind) See [Artist's Conception of the Heliospheric Current Sheet http://quake.stanford.edu/~wso/gifs/HCS.html&#093.
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The Heliospheric current sheet, the largest structure in the Solar SystemSee [A Star with two North Poles], resulting from the influence of the Sun's rotating magnetic field on the plasma in the interplanetary medium (Solar Wind) See [Artist's Conception of the Heliospheric Current Sheet http://quake.stanford.edu/~wso/gifs/HCS.html].

Plasma parameters can take on values varying by many orders of magnitude, but the properties of plasmas with apparently disparate parameters may be very similar (see plasma scaling). The following chart considers only conventional atomic plasmas and not exotic phenomena like quark gluon plasmas:

Typical ranges of plasma parameters: orders of magnitude (OOM)
CharacteristicTerrestrial plasmasCosmic plasmas
Size
in metres
10−6 m (lab plasmas) to
102 m (lightning) (~8 OOM)
10−6 m (spacecraft sheath) to
1025 m (intergalactic nebula) (~31 OOM)
Lifetime
in seconds
10−12 s (laser-produced plasma) to
107 s (fluorescent lights) (~19 OOM)
101 s (solar flares) to
1017 s (intergalactic plasma) (~17 OOM)
Density
in particles per
cubic metre
107 m-3 to
1032 m-3 (inertial confinement plasma)
1030 (stellar core) to
100 (i.e., 1) (intergalactic medium)
Temperature
in kelvins
~0 K (Crystalline non-neutral plasmaSee [The Nonneutral Plasma Group] at the University of California, San Diego) to
108 K (magnetic fusion plasma)
102 K (aurora) to
107 K (Solar core)
Magnetic fields
in teslas
10−4 T (Lab plasma) to
103 T (pulsed-power plasma)
10−12 T (intergalactic medium) to
1011 T (near neutron stars)

Degree of ionization

For plasma to exist, ionization is necessary. The degree of ionization of a plasma is the proportion of atoms which have lost (or gained) electrons, and is controlled mostly by the temperature. Even a partially ionized gas in which as little as 1% of the particles are ionized can have the characteristics of a plasma (i.e. respond to magnetic fields and be highly electrically conductive). The degree of ionization, α is defined as α = ni/(ni + na) where ni is the number density of ions and na is the number density of neutral atoms.

Temperatures

The central electrode of a plasma lamp, showing a glowing blue plasma streaming upwards. The colors are a result of the relaxation of electrons in excited states to lower energy states after they have recombined with ions. These processes emit light in a spectrum characteristic of the gas being excited.
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The central electrode of a plasma lamp, showing a glowing blue plasma streaming upwards. The colors are a result of the relaxation of electrons in excited states to lower energy states after they have recombined with ions. These processes emit light in a spectrum characteristic of the gas being excited.

Plasma temperature is commonly measured in Kelvin or electron volts, and is (roughly speaking) a measure of the thermal kinetic energy per particle. In most cases the electrons are close enough to thermal equilibrium that their temperature is relatively well-defined, even when there is a significant deviation from a Maxwellian energy distribution function, for example due to UV radiation, energetic particles, or strong electric fields. Because of the large difference in mass, the electrons come to thermodynamic equilibrium among themselves much faster than they come into equilibrium with the ions or neutral atoms. For this reason the ion temperature may be very different from (usually lower than) the electron temperature. This is especially common in weakly ionized technological plasmas, where the ions are often near the ambient temperature.

Temperature controls the degree of plasma ionization. In particular, plasma ionization is determined by the electron temperature relative to the ionization energy (and more weakly by the density) in accordance with the Saha equation. A plasma is sometimes referred to as being hot if it is nearly fully ionized, or cold if only a small fraction (for example 1%) of the gas molecules are ionized (but other definitions of the terms hot plasma and cold plasma are common). Even in a "cold" plasma the electron temperature is still typically several thousand degrees. Plasmas utilized in plasma technology ("technological plasmas") are usually cold in this sense.

Densities

Next to the temperature, which is of fundamental importance for the very existence of a plasma, the most important property is the density. The word "plasma density" by itself usually refers to the electron density, that is, the number of free electrons per unit volume. The ion density is related to this by the average charge state [\langle Z\rangle] of the ions through [n_e=\langle Z\rangle n_i]. (See quasineutrality below.) The third important quantity is the density of neutrals [n_0]. In a hot plasma this is small, but may still determine important physics. The degree of ionization is [n_i/(n_0+n_i)].

Potentials

Lightning is an example of plasma present at Earth's surface. Typically, lightning discharges 30 thousand amps, at up to 100 million volts, and emits light, radio waves, x-rays and even gamma rays See [Flashes in the Sky: Earth's Gamma-Ray Bursts Triggered by Lightning]. Plasma temperatures in lightning can approach 28,000 kelvins and electron densities may exceed 1024/m3.
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Lightning is an example of plasma present at Earth's surface. Typically, lightning discharges 30 thousand amps, at up to 100 million volts, and emits light, radio waves, x-rays and even gamma rays See [Flashes in the Sky: Earth's Gamma-Ray Bursts Triggered by Lightning]. Plasma temperatures in lightning can approach 28,000 kelvins and electron densities may exceed 1024/m3.

Since plasmas are very good conductors, electric potentials play an important role. The potential as it exists on average in the space between charged particles, independent of the question of how it can be measured, is called the plasma potential or the space potential. If an electrode is inserted into a plasma, its potential will generally lie considerably below the plasma potential due to the development of a Debye sheath. Due to the good electrical conductivity, the electric fields in plasmas tend to be very small. This results in the important concept of quasineutrality, which says that it is a very good approximation to assume that the density of negative charges is equal to the density of positive charges over large volumes of the plasma ([n_e=\langle Z\rangle n_i]), but on the scale of the Debye length there can be charge imbalance. In the special case that double layers are formed, the charge separation can extend some tens of Debye lengths.

The magnitude of the potentials and electric fields must be determined by means other than simply finding the net charge density. A common example is to assume that the electrons satisfy the Boltzmann relation, [n_e \propto e^]. Differentiating this relation provides a means to calculate the electric field from the density: [\vec = (k_BT_e/e)(\nabla n_e/n_e)].

It is, of course, possible to produce a plasma that is not quasineutral. An electron beam, for example, has only negative charges. The density of a non-neutral plasma must generally be very low, or it must be very small, otherwise it will be dissipated by the repulsive electrostatic force.

In astrophysical plasmas, Debye screening prevents electric fields from directly affecting the plasma over large distances (ie. greater than the Debye length). But the existence of charged particles causes the plasma to generate and be affected by magnetic fields. This can and does cause extremely complex behavior, such as the generation of plasma double layers, an object that separates charge over a few tens of Debye lengths. The dynamics of plasmas interacting with external and self-generated magnetic fields are studied in the academic discipline of magnetohydrodynamics.

Magnetization

A plasma in which the magnetic field is strong enough to influence the motion of the charged particles is said to be magnetized. A common quantitative criterion is that a particle on average completes at least one gyration around the magnetic field before making a collision: [\omega_/\nu_ > 1]. It is often the case that the electrons are magnetized while the ions are not. Magnetized plasmas are anisotropic, meaning that their properties in the direction parallel to the magnetic field are different from those perpendicular to it. While electric fields in plasmas are usually small due to the high conductivity, the electric field associated with a plasma moving in a magnetic field is not affected by Debye shielding.Richard Fitzpatrick, Introduction to Plasma Physics, [Magnetized plasmas]

Comparison of plasma and gas phases

Plasma is often called the fourth state of matter. It is distinct from the three lower-energy phases of matter; solid, liquid, and gas, although it is closely related to the gas phase in that it also has no definite form or volume. There is still some disagreement as to whether a plasma is a distinct state of matter or simply a type of gas. Most physicists consider a plasma to be more than a gas because of a number of distinct properties including the following:

Property Gas Plasma
Electrical Conductivity Very low
The air is quite a good insulator, as demonstrated by high voltage electric power transmission where wires typically carry 110,000 Volts. High voltages may lead to electrical breakdown, as can lower pressures in fluorescent lights and neon signs
Very high
  1. For many purposes the electric field in a plasma may be treated as zero, although when current flows the voltage drop, though small, is finite, and density gradients are usually associated with an electric field according to the Boltzmann relation.
  2. The possibility of currents couples the plasma strongly to magnetic fields, which are responsible for a large variety of structures such as filaments, sheets, and jets.
  3. Collective phenomena are common because the electric and magnetic forces are both long-range and potentially many orders of magnitude stronger than gravitational forces.
Independently acting species One
All gas particles behave in a similar way, influenced by gravity, and collisions with one another
Two or three
Electrons, ions, and neutrals can be distinguished by the sign of their charge so that they behave independently in many circumstances, having different velocities or even different temperatures, leading to phenomenon such as new types of waves and instabilities
Velocity distribution
right
Maxwellian
The velocity distributes of all gas particles has a characteristic shape:
May be non-Maxwellian
Whereas collisional interactions always lead to a Maxwellian velocity distribution, electric fields influence the particle velocities differently. The velocity dependence of the Coulomb collision cross section can amplify these differences, resulting in phenomena like two-temperature distributions and run-away electrons.
Interactions Binary
Two-particle collisions are the rule, three-body collisions extremely rare.
Collective
Each particle interacts simultaneously with many others. These collective interactions are about ten times more important than binary collisions.

Complex plasma phenomena

The remnant of Tycho's Supernova, a huge ball of expanding plasma. The blue outer shell arises from X-ray emission by high-speed electrons.
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The remnant of Tycho's Supernova, a huge ball of expanding plasma. The blue outer shell arises from X-ray emission by high-speed electrons.

Although the underlying equations governing plasmas are relatively simple, plasma behaviour is extraordinarily varied and subtle: the emergence of unexpected behaviour from a simple model is a typical feature of a complex system. Such systems lie in some sense on the boundary between ordered and disordered behaviour, and cannot typically be described either by simple, smooth, mathematical functions, or by pure randomness. The spontaneous formation of interesting spatial features on a wide range of length scales is one manifestation of plasma complexity. The features are interesting, for example, because they are very sharp, spatially intermittent (the distance between features is much larger than the features themselves), or have a fractal form. Many of these features were first studied in the laboratory, and have subsequently been recognised throughout the universe. Examples of complexity and complex structures in plasmas include:

Ultracold plasma

Saturn's rings in which certain effects have been suggested are due to dusty plasmasHoranyi, M. et al, &#091;Dusty Plasma Effects in Saturn's Rings&#093; (2004) American Geophysical Union, Fall Meeting 2004, abstract #P52A-07. See also Blikoh, P. V. et al &#091;pokes in the Saturn's Ring as Solutions in Dusty Plasma&#093; (1994) Dusty and Dirty Plasmas, Noise, and Chaos in Space and in the Laboratory. Edited by Hiroshi Kikuchi. <a href=ISBN 0-306-44839-4. Published by Plenum Press, New York, 1994, p.29 (false colour image)See &#091;Saturn: Rings&#093;" title="Saturn's rings in which certain effects have been suggested are due to dusty plasmasHoranyi, M. et al, &#091;Dusty Plasma Effects in Saturn's Rings&#093; (2004) American Geophysical Union, Fall Meeting 2004, abstract #P52A-07. See also Blikoh, P. V. et al &#091;pokes in the Saturn's Ring as Solutions in Dusty Plasma&#093; (1994) Dusty and Dirty Plasmas, Noise, and Chaos in Space and in the Laboratory. Edited by Hiroshi Kikuchi. ISBN 0-306-44839-4. Published by Plenum Press, New York, 1994, p.29 (false colour image)See &#091;Saturn: Rings&#093;" />
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Saturn's rings in which certain effects have been suggested are due to dusty plasmasHoranyi, M. et al, [Dusty Plasma Effects in Saturn's Rings] (2004) American Geophysical Union, Fall Meeting 2004, abstract #P52A-07. See also Blikoh, P. V. et al [pokes in the Saturn's Ring as Solutions in Dusty Plasma] (1994) Dusty and Dirty Plasmas, Noise, and Chaos in Space and in the Laboratory. Edited by Hiroshi Kikuchi. ISBN 0-306-44839-4. Published by Plenum Press, New York, 1994, p.29 (false colour image)See [Saturn: Rings]

It is possible to create ultracold plasmas, by using lasers to trap and cool neutral atoms to temperatures of 1 mK lower. Another laser then ionizes the atoms by giving each of the outermost electrons just enough energy to escape the electrical attraction of its parent ion.

The key point about ultracold plasmas is that by manipulating the atoms with lasers, the kinetic energy of the liberated electrons can be controlled. Using standard pulsed lasers, the electron energy can be made to correspond to a temperature of as low as 0.1 K ­ a limit set by the frequency bandwidth of the laser pulse. The ions, however, retain the millikelvin temperatures of the neutral atoms. This type of non-equilibrium ultracold plasma evolves rapidly, and many fundamental questions about its behaviour remain unanswered. Experiments conducted so far have revealed surprising dynamics and recombination behaviour that are pushing the limits of our knowledge of plasma physics.

Non-neutral plasma

The strength and range of the electric force and the good conductivity of plasmas usually ensure that the density of positive and negative charges in any sizeable region are equal ("quasineutrality"). A plasma that has a significant excess of charge density or that is, in the extreme case, composed of only a single species, a called a non-neutral plasma. In such a plasma, electric fields play a dominant role. Examples are charged particle beams, an electron cloud in a Penning trap, and positron plasmasR. G. Greaves, M. D. Tinkle, and C. M. Surko, "[Creation and uses of positron plasmas]", Physics of Plasmas -- May 1994 -- Volume 1, Issue 5, pp. 1439-1446.

Dusty plasma and grain plasma

A dusty plasma is one containing tiny charged particles of dust (typically found in space) that also behaves like a plasma. A plasma containing larger particles is called a grain plasma.

Mathematical descriptions

The complex self-constricting magnetic field lines and current paths in a field-aligned Birkeland current that may develop in a plasma See &#091;Evolution of the Solar System&#093;, 1976)
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The complex self-constricting magnetic field lines and current paths in a field-aligned Birkeland current that may develop in a plasma See [Evolution of the Solar System]'', 1976)

To completely describe the state of a plasma, we would need to write down all the particle locations and velocities, and describe the electromagnetic field in the plasma region. However, it is generally not practical or necessary to keep track of all the particles in a plasma. Therefore, plasma physicists commonly use less detailed descriptions known as models, of which there are two main types:

Fluid

Fluid models describe plasmas in terms of smoothed quantities like density and averaged velocity around each position (see Plasma parameters). One simple fluid model, magnetohydrodynamics, treats the plasma as a single fluid governed by a combination of Maxwell's Equations and the Navier Stokes Equations. A more general description is the two-fluid picture, where the ions and electrons are described separately. Fluid models are often accurate when collisionality is sufficiently high to keep the plasma velocity distribution close to a Maxwell-Boltzmann distribution. Because fluid models usually describe the plasma in terms of a single flow at a certain temperature at each spatial location, they cannot capture velocity space structures like interpenetrating beams, or resolve wave-particle effects.

Kinetic

Kinetic models describe the particle velocity distribution function at each point in the plasma, and therefore do not need to assume a Maxwell-Boltzmann distribution. A kinetic description is often necessary for collisionless plasmas. There are two common approaches to kinetic description of a plasma. One is based on representing the smoothed distribution function on a grid in velocity and position. The other, known as the particle-in-cell (PIC) technique, includes kinetic information by following the trajectories of a large number of individual particles. Kinetic models are generally more computationally intensive than fluid models.

Fields of active research

Hall effect thruster. The electric field in a plasma double layer is so effective at accelerating ions, that electric fields are used in ion drives
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Hall effect thruster. The electric field in a plasma double layer is so effective at accelerating ions, that electric fields are used in ion drives

This is just a partial list of topics. A more complete and organised list can be found on the Web site for Plasma science and technology Web site for [Plasma science and technology].

Footnotes

A candle flame. Fire can be considered to be a very low temperature partial plasma.
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A candle flame. Fire can be considered to be a very low temperature partial plasma.

See also

External links

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