Viscoelasticity
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A viscoelastic material is one in which:
- hysteresis is seen in the stress-strain curve.
- stress relaxation occurs: step constant strain causes decreasing stress
- creep occurs: step constant stress causes increasing strain
Overview
Early scientists defined matter as a solid, liquid, or gas. They found that some materials fit in more than one of these phases. For instance, honey is a good example of a material with the physical properties of both a solid and a liquid. If one allows honey to flow from a container and then quickly tips the container up, a portion of the honey will be pulled back into the container. Liquids don’t typically respond to tensile force or pulling force. Scientists defined this material as viscoelastic because it exhibited the characteristics of a viscous liquid and an elastomeric solid. Silly putty, chewing gum, and polyurethane memory foam are also examples of viscoelastic materials.
Almost all polymers exhibit viscoelastic behavior. Polymers (and other viscoelastic materials) behave more like solids at low temperatures and fast deformation speeds. They are more like liquids at high temperatures and slow deformation speeds.
Types of viscoelasticity
Linear viscoelasticity is when the function is separable in both creep response and load. All linear viscoelastic models can be represented by a Volterra equation connecting stress and strain:
- [\epsilon(t)= \frac }+ \int_0^t K(t-t^\prime) \sigma(t^\prime) d t^\prime]
- [\sigma(t)= E_\epsilon(t)+ \int_0^t F(t-t^\prime) \epsilon(t^\prime) d t^\prime]
- t is time
- [\sigma (t)] is stress
- [\epsilon (t)] is strain
- [E_] and [E_] are instantaneous elastic moduli for creep and relaxation
- K(t) is the creep function
- F(t) is the relaxation function
Nonlinear viscoelasticity is when the function is not separable. It is usually happens when the deformations are large or if the material changes its properties under deformations.
See also
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